高效不对称催化反应的开发 |
| Asymmetric Allylic Substitution |
Asymmetric Wacker-type Oxidative Cyclization |
Asymmetric Hydrogenation |
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7.1 Asymmetric Allylic Substitution
7.1.1 Enamines as Nucleophilic Reagents |
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7.1.2 Enamines Generated in situ |
7.1.3 Allylic C-N Cleavage under Mild Conditions |
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| 7.2 Wacker-type Oxidative Cyclization |
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| 7.2.1 Pd-Quinox Catalyzed Aza-Wacker Type Cyclization |
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| Ref: TL,2010,51,5124 |
7.2.2 Switchable Regioselective Pd-Catalyzed Aerobic Aza-Wacker Cyclization--Ligands effect! |
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7.2.3 The First Enantioselective Aza-Wacker-Type Reactions for Construction of α-Tertiary Amines |
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7.3 Asymmetric Hydrogenation |
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| 7.4 Asymmetric Organocatalyses |
The First Asymmetric Organocatalyzed Phsphorylation |
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